From Sue Chastain,
Your Guide to Graphics Software.
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You may unzip the brush nibs to any folder. When you unzip each set, you will get two files - a *.nib file and a *.msk file. You need to keep both of these files in the same folder in order for the nibs to work. I prefer to keep my brushes in a subdirectory of my Photo-Paint folder named brushes, but they can be located anywhere. Select the Paint Tool in Photo-Paint, then if it's not open already, open the Tool Settings roll-up (Ctrl-F8). If your tool settings roll-up does not look like the one shown below, you will need to click the small arrow labeled "1" in the diagram below in order to see all of the options. Next, click the small arrow labels "2" in the diagram, and choose Load Nib File or Append Nib file from the menu, then select the nib you'd like to use from the drop down selection box in the roll-up.